The Puerto Rico Radiosondes CPEX-AW dataset consists of atmospheric pressure, atmospheric temperature, relative humidity, wind speed, and wind direction measurements. These measurements were taken from the DFM-09 Radiosonde instrument during the Convective Processes Experiment – Aerosols & Winds (CPEX-AW) field campaign. CPEX-AW was a joint effort between the US National Aeronautics and Space Administration (NASA) and the European Space Agency (ESA) with the primary goal of conducting a post-launch calibration and validation activities of the Atmospheric Dynamics Mission-Aeolus (ADM-AEOLUS) Earth observation wind Lidar satellite in St. Croix, U.S. Virgin Islands. Data are available from August 24, 2021 through September 28, 2021 in ASCII format, with associated browse Skew-T graphs in PNG format.